40th Annual Meeting, Objects Session, May 11th, “The Treatment of a Mi’kmaq Box Made of Birchbark, Porcupine Quills, and Iron-Dyed Spruceroot”, Carole Dignard

The multi-step treatment of a Mi’kmaq birchbark box was outlined in this talk presented by Season Tse. The circular box with four stacks of rings is made of birchbark and decorated with dyed spruceroot and porcupine quills. Before treatment, it was exhibiting significant instability due to a deformation of the lid, the separation of the rim from the lid, and localized deterioration of the dark brown dyed spruceroot. There were also reported losses in the birchbark, unknown instability of dye components to light, losses to the spruceroot, and overall surface dirt.

The treatment began with a cleaning of the quillwork with saliva. This step revealed the brilliance of the blue-dyed quillwork and the presence of yellow-dyed quillwork previously unnoticed. The sensitivity of the dyes to light damage was tested using microfade tests with a Blue Wool dye scale ranging from 1-8. The dyes were found to between 3-4, which indicates that the dyes would survive 100 years at 50 lux for 8 hours a day before noticeable fading occurred.

The lid of the box was deformed and warping. After testing using deformed samples of birchbark, they found the appropriate solvent and pressure parameters to treat the deformity. A methanol vapor chamber was used under 6 psi vacuum conditions for three days to reform the lid. The treatment was mostly successful though some springing occurred.  Broken spruceroot was stabilized, paper pulps fills were used for the loss of birchbark, and the lid was attached to the rim with Japanese tissue paper hinges.

The investigation and treatment of the dark brown colored spruceroot could be considered the highlight of the talk. Through their investigation into the colorants of the material they found that the colorant had both iron (II) ions and tannins present. This combination has been reported time and again as the source for severe deterioration of dyed cellulosic material. The concentration of iron (II) ions were identified and monitored throughout the treatment with iron indicator paper. To stabilize this deterioration they choose calcium-phytate solution, developed by CCI, to complex with the iron thus arrest the oxidation of the spruceroot material.  Because the box could not be immersed in to the solution the application was with brush. After each application the ion content was monitored. They found that five applications were enough to stabilize. However, the application of the solution was not without complications and risks. The spruceroot swelled during the application and staining of neighboring spruce root occurred due to migration of the iron ions.

 

 

 

40th Annual Meeting, Wooden Artifacts Session, May 11 “Conservation Training at the Forbidden City”, Antoine Wilmering

Ton Wilmering, Senior Program Officer at the Getty Foundation, spoke about the the World Monument Fund’s new conservation training program it has developed at the Forbidden City in Beijing, China as part of its collaborative conservation program for the Qianlong Gardens in the Forbidden City. The gardens, a series of 27 pavillions and courtyards built by the Qianlong Emperor between 1771 and 1776 within the Forbidden City are an extraordinary example of Qian Dynasty decorative arts, and reflect the emperor’s broad cultural tastes and knowledge. I had the privilege of seeing the traveling exhibition of furniture and other objects from the Qianlong Gardens at the Peabody Essex Museum in Salem, MA in 2010, and the furniture and interiors on view were beautiful, exhibiting incredible craftsmanship.

The World Monument Fund is focused on funding projects with capacity-building components, and in conjunction with their conservation program in the Qianlong Gardens, in 2009 they established an new training program in the Forbidden City known as Conservation Resources for Architectural Interiors/Furniture and Training, or CRAFT. The program is designed to provide on-the-job training in both traditional craft practices and modern conservation techniques and science. Participants were selected from among current staff members of the Forbidden City complex, and include carpenters, collections care specialists, curators, architects and scientists. Current craft practitioners in China often have little knowledge of past techniques or history, and the program was designed to introduce them to craft history using historic Chinese cabinet making manuals. The program focuses on critical thinking as well as hand skills, and areas of study include scientific principles, history of conservation ethics, worker safety, drawing and drafting using both traditional and CAD techniques, materials technology, tool making, and joinery.

The program has made efforts to include Chinese faculty wherever possible, and Chinese wood species specialists and organic and inorganic chemists have taught in the program. The WMF found that many of the resources and people needed in the program were available in Beijing (in fact lots of conservation literature has been translated into Mandarin), but the WMF needed to make the connections with local libraries and scientists to bring them into the project. Other participants in the training program have included Susan Buck (cross-section analysis), and Chris McGlinchey (adhesives), and Behrooz Salimnejad (gilding) among others, as well as Ton, Rick Kershner and Greg Landrey, who the WMF brought in initially to design a space for the program and develop the curriculum.

Ton pointed out that the furniture on view in the traveling exhibition from the Qianlong Gardens which came to the US had not been worked on by participants in the CRAFT program. Instead, the Forbidden City bureaucracy had contracted out the restoration of that furniture, and it often involved practices that conflicted with modern conservation ethics. I was interested in the cultural differences exhibited by the Chinese participants. Ton told how the students all liked to work together on a project, showing a picture of four students sitting around a table, cleaning it with swabs together.

Ton also talked about the difficulties the program has experienced. Because the participants are employees working in the Forbidden City (remember, the program is on-the-job training), they are frequently called away to their regular jobs, which can be disruptive. Continuous supervision of the program by a trained conservator has also bee difficult. Many of the original participants have had to – or have chosen to – drop out, and currently about half the original class are still participating. Interestingly, it is the carpenters and architects who have stayed, not the collections care specialists.

After talking about the CRAFT program, Ton briefly discussed another initiative the Getty Foundation is involved in, to facilitate the transfer (and retention) of skills and knowledge in the structural conservation of panel paintings. Many of the most skilled practitioners in the conservation of these wooden panels are approaching retirement age, and the Getty Foundation has begun a 6 year initiative to set up apprenticeships with these practitioners for post-graduate, mid-career and senior conservators of wooden artifacts. The program is designed to have a broad geographic distribution, to include participants in Eastern and Western Europe, as well as the US and UK, presumably.

 

AIC’s 40th Annual Meeting – Objects Session, May 11, “Made in L.A.” by Rachel Rivenc

The original topic of this talk shifted from the analysis of sculpture created by the “Finish Fetish” artists using ATR (attenuated total reflection) to a discussion of the materials and methods of fabrication employed by three of these artists: Craig Kauffman, John McCracken, and Larry Bell. Though not accepted by the artists themselves, “Finish Fetish” was a name bestowed upon a group working in the L.A. area in the 1960s referring to the cool, yet pristinely finished surfaces that were characteristic of their art. Rachel noted that care must be given to preserving the signature surfaces, thus any analytical investigations required the use of non-invasive techniques only. The materials examination was augmented by interviews with artists when possible, as well as archival documents.

Craig Kauffman, one of the first artists to use plastics in the L.A. art community, converted industrial fabrication methods into his practice. Heavily influenced by Marcel Duchamp, his early work involved painting, typically with clean lines, on the back of acrylic sheets composed of poly(methyl methacrylate), confirmed by ATR analysis. By 1964, he had begun shaping the acrylic sheets by vacuum forming, collaborating with a manufacturer. The acrylic was heated in an oven until it softened, then shaped on a mold to create shallow reliefs. Kauffman’s sketches reveal plans for fiberglass molds with wooden supports, which were especially necessary for his later experimentations with depth and complexity. The transparent shells were subsequently painted, using thick rubber masks to create crisp lines. Later, he created a feathered look by spraying the paint over a cardboard mask, which served to soften the lines. He eventually shifted from solvent-borne acrylic-based paint, an ethyl methacrylate/methyl acrylate co-polymer, to nitrocellulose paints, since the solvent-based paints caused the substrate to craze and crack.

Rachel went on to discuss the technique and materials of John McCracken, who is reported to have said he wanted his sculptures to look as if they were “made of color.” They generally consisted of wooden planks coated in a layer of fiberglass, followed by a primer and various layers of paint, later switching to polyester resin application instead of paint. To make grooves in the surface, he would mask the lines with painter’s tape, then coat exposed surface in the polyester resin mixed with pigment. He consistently jotted down ideas and sketches before producing technical drawings, and even kept a notebook recording the varying temperatures and amounts of catalyst used for the resin as he experimented, making note of how it affected the working time, as well as the properties of the resulting work. Regardless of the conditions, the application of resin to the surface of the planks required an experienced and steady hand in order to avoid the evolution of bubbles in the resin layer (as any novice conservator embedding their first few paint samples for cross-sections knows!). The final step involved sanding of the surface to a smooth sheen.

The last artist Rachel broached was Larry Bell, who worked not with plastic, but with glass. Originally a painter, he would add mirrors to his compositions to introduce volume, eventually deciding that he wanted to work exclusively with volume. He worked often with plywood, mirror parts, and paint, though he increasingly favored glass, such that his paint became instead the effect of light as it was manipulated by the glass. In 1962, he began experimenting with the vacuum deposition of thin films to the glass, soon after which he bought a secondhand machine to execute the process himself in 1966. This purchase allowed him the freedom to create larger panels, which also corresponded with a shift into more environmental art. The vacuum chamber heated the metal under vacuum to a temperature at which the metal vaporized and was deposited on the surface of the glass as a micron-thin film. The three metals most commonly used by Bell were aluminum, silicon monoxide, and nickel-chromium alloys, otherwise known as ‘Inconel.’ The thin film of metal influences the way light is reflected, refracted, and transmitted through the glass. Bell also experimented with changing the temperature and combining metals, all while monitoring the chamber through a window to assess the changes. Rachel noted that Bell, the only artist alive of the three discussed, is actively involved in the conservation of his work, providing conservators with replacement panels when they break.

The above represents but a small portion of the project embarked upon by the GCI (Getty Conservation Institute), a study of the materials and working methods of these and other artists active in the LA area during the postwar period who borrowed from modern industry. The study is a part of both the Pacific Standard Time initiative that included a recent set of exhibitions across Southern California sponsored in part by the The Getty. It also represents the GCI Modern and Contemporary Art research initiative. Future plans include a publication to disseminate the work, a short video, and an exploration of practical applications for the information gained, such as ways to mend cracked and chipped polyester and acrylic resin. Ultimately, the research of Rachel and her colleagues, Emma Richardson and Tom Learner, will hopefully help facilitate treatment decision-making for conservators working with modern and contemporary artwork.

40th Annual Meeting, Wooden Artifacts Session, May 11 “The Establishment of Collaborative Platforms in Protecting and Conserving of the Global Cultural Heritage”, Dr. Hany Hanna

Dr. Hany Hanna, who is the General Director of Conservation for the Helwan, El-Saf and Afteh Sectors of the Supreme Council of Antiquities in Egypt, delivered a general call for increased levels of attention on a local, national, regional and global scale to the protection and conservation of global heritage. While his talk did not relate to wooden artifacts specifically in any way, it was directly related to the theme of the Annual Meeting as a whole, and since Dr. Hanna specializes in the conservation of wooden objects and has spoken to our group in the past, no doubt he felt WAG was the appropriate venue for his talk this year.

Dr. Hanna began by defining cultural heritage as including both the tangible and intangible. Tangible heritage includes:

  1. Cultural
  2. Natural
  3. Cultural Landscapes
Intangible heritage includes:
  1. Practical experience
  2. Knowledge
  3. Skills
He pointed out that cultural heritage is priceless for humanity as a whole, as well as for nations and groups. It both strengthens identity within groups, as well as respect for and appreciation of other groups. Dr. Hanna discussed the fact that while great strides have been made on a global scale in protecting our global cultural heritage through education, advances in technology, and the development of new facilities and international partnerships, more must be done to protect cultural heritage form man-made and natural threats. In general, he called for more training, more investment in research and education, as well as facilities to carry out this research and training, and more international cooperation and partnerships.
At the same time, Dr. Hanna encouraged self reliance on the part of governments, NGO’s and universities in individual countries. His point seemed to be that while networking, cooperation and partnerships are vital for the preservation of global cultural heritage, local action and raising local public awareness are the most effective means of achieving preservation goals of emergency preparedness and recovery, risk and damage assessment, and reconstruction and restoration.
In general the ideas and approaches outlined by Dr. Hanna are completely in accord with the thinking of the US conservation community. But it was encouraging to hear them being expressed by a colleague from Egypt. Dr Hanna made two points which were somewhat more surprising. He called for what amounts to an international certification program, validated by local governments but defined by professional organizations, which would include measures to protect against malpractice. I for one had not heard this idea suggested before, and I’m not sure US conservators are ready to embrace such an idea, given our recent decision on a US certification program. But it may reflect the different experience of Dr Hanna in the practice of responsible conservation.
Dr. Hanna also called for the integration of cultural heritage and conservation issues with other economic sectors, suggesting that this would aid social and economic development. This seems to me to be essentially the same argument the Anne-Imelda Radice made in her address to the general session. But in discussing this, Dr. Hanna suggested that conservation training needed to be based “on every day life on a wider level”.  By this I took him to mean that conservation training needs to be related to and made relevant in the lives of the people living with the cultural heritage the training program is intended to protect. This seems an eminently sensible suggestion, and relates Dr. Hanna’s talk to the next talk in the WAG session by Ton Wilmering, discussing the World Monuments Fund’s new conservation training program in the Forbidden City in Beijing China, which I will discuss in my next blog.

AIC’s 40th Annual Meeting, Research and Technical Studies Session, May 10, “Digital imaging analysis of writing materials using Photoshop Assisted Spectroscopy”, by Kristi Davenport, Holly Herro, Peter Gabriele

NB: Before I try to blog about this talk, I need to say that…well, we didn’t really ever get to discussing Photoshop Assisted spectroscopy! Meaning, this blog will contain some interesting tidbits but you won’t be learning much about this technique or how you might use it in your lab/institution. Sorry!

The project highlighted in this talk was the analysis of the logbooks and writings of Dr. Nirenberg, a Nobel Laureate. Dr. Nirenberg cracked the genetic code (our DNA) and his writings are considered a national treasure. The bad news is that all of his writings were made using ballpoint ink and ballpoint inks are notoriously fugitive. This project used the Photoshop Assisted spectroscopy (is this just kind of like hyperspectral imaging???), and interviews with Dr. Nirenberg’s former technicians to figure out what different markings mean in the logbooks and writings (eg, there are occasionally red marks in the books which were used by Dr. Nirenberg to indicate points/data/results of interest). Also, drops/stains on the charts/files turned out to be because solvent was accidentally dropped onto the books during lab experiments.

http://en.wikipedia.org/wiki/Marshall_Warren_Nirenberg

INKS
* First ballpoint pen was patented in 1818; the pens were used to mark leather
* The inks contained within are not very archival and weren’t designed to be
* Ball ink is used by some artists and it will fade with time
* There are a lot of components in ink; dyes and pigments; solvents, resins, emulsifying agents, lubricants, viscosity modifiers; optical additives; anti-corrosives;
* The rolling ball at the tip of a ballpoint pen is supposed to plow through the ink, pushing it onto/into the paper. You can get buildup of ink at the front of the pen if the pen doesn’t work well and results in those goopy clumps you sometimes get;
*As soon as the ink comes out from the interior, the ink is oxidizing
*The roller ball can pick up residue from the surface of the paper and roll it back into the ink reservoir – this is not good because you can get a build up of garbage interacting with the ink.
*All new inks that are out there have fluorescing agents in them – to make ink look brighter with the artificial lighting used in most office spaces – this is a way you can differentiate modern inks from older ones when examining documents
* ballpoint ink pens is a $20 Billion/year business; the entire idea is for you to keep buying these products
* Before 1949 – inks in pens were oil based; these inks are very stable and you can use this information to help you differentiate when inks were applied to a substrate
* black ink is black because it has all the chromophores in it; when it degrades/separates, it changes color; other colors fade
* All inks have different fingerprints

When you get a historic document, you don’t know starting point of original ink. But you can look at the current state of the ink and you can start to understand degradation process.

SCANNING DOCUMENTS
A scanner is actually a spectrometer. Every pixel has an RGB value, but the computer mixes the colors for your eye. However, you can use those same values in a more creative way: If you consider the RGB values as values for a three dimensional space, you can use the values to plot them on a 3D map and track different types of inks used on historic documents.

AIC’s 40th Annual Meeting – RATS morning session, May 10, “Atomic Layer Deposition (ALD) films as protective coatings for silver”, by Amy Marquardt, Glenn Gates, Eric Breitung, Richard Ash, Gary Robloff, Ray Phaneuf, and Terry Drayman-Weisser*

*nb: the title of this talk, the author list, and author order all changed from what was published in the program. If I have left out an author name, I apologize.

The focus of this talk was to discuss the application of atomic layer deposited films of aluminum oxide (Al2O3) onto sterling silver surfaces. Ultimately, it is hoped that this process will be refined for use with sterling silver art objects in museums.

The overarching goals of this project are to find a coating for silver that is long lived; slows the diffusion of sulfur to the surface of the art object (I learned this fact at the presentation by Zeev Rosenzweig at the RATS luncheon); can be rapidly applied and covers the object homogeneously; is removable; and is less labor intensive than manual application and mechanical polishing.

(wow, that’s a lot!)

The University of Maryland has a “BENEQ TFS 500”, a commercially available atomic layer deposition (ALD) machine/instrument, to deposit thin film coatings on anything that is placed inside of it.
http://www.beneq.com/tfs-500.html

Awesome facts of this instrument:
• Samples placed in the instrument can touch one another and it won’t affect deposition;
• You can coat MANY samples all at the same time
• You can control the thickness of the layer you deposit onto the objects you place inside the instrument, down to the nanometer (nm) thicknesses
• Coatings are incredibly uniform
• The films made are dense (ie, tightly compacted), and these types of films make good vapor barriers
• Coating will go into very small crevices and tool marks
• Tailoring thickness allows you to control optical properties
• It can take a mere 1 hour to make a coating that is 100 nm thick

The project is currently examining whether aluminum oxide coatings perform better than nitrocellulose ones. They used accelerated aging studies (40°C, 30-50% RH, 20 ppm hydrogen sulfide pumped through a sealed chamber) on coated samples and performed Tarnish Rate Analysis (never heard of this!! measure color of tarnish; correlate to thickness of tarnish layer), X-ray photon spectroscopy (XPS), secondary ion mass time of flight mass spectrometry (SIMS-TOF), and atomic force microscopy (AFM) to analyze this.

RESULTS and CONCLUSIONS:
* A 80 nm aluminum oxide coating outperformed a microns thick nitrocellulose coating because it is more tarnish resistant than nitrocellulose.

* They said that that these results are very fresh and new but that the aluminum oxide coatings are removable with a minimal loss of surface copper and silver using dilute sodium hydroxide (NaOH) but that you have to be careful about the concentration of the NaOH because it can selectively remove copper over silver from the sterling silver alloy itself. But that we should all relax because the amount of copper or silver being removed is on the nanoscale.

Q&A session:

Comment: Eric presented removability study with weak NaOH compared to data from Glenn (I don’t know if this work is published or has been presented elsewhere), who used three different chalks (all of which were in the lab);

Q: is this atomic layer deposition instrument expensive?

A reactor costs…$500K. BUT you can build one or buy the parts separate and assemble one yourself; not rocket science to build one; there is a place in Cambridge (MA? England?) that sells on for <$100K; you can make a homemade one for ~$50K

Q7: how long will coating last?

At least 20 years; a guess, no hard evidence

One facet of this project is to build coatings even better than aluminum oxide

TERRY Weissman: lot of the current results presented here are theorhetical; we will be getting into more of the conservation issues as time goes along;

Also, we knew that NaOH would affect the copper; but often times, art objects are already Cu depleted; We might find a better solvent in the future

AIC’s 40th Annual Meeting – RATS morning session, May 10, “Progress in the investigation of silicone rubbers and their residues”, by Kasey L. Hamilton, Adriana Rizzo, and Anna Serotta

The focus of this presentation was to address problems associated with the use of slow and quick setting silicone rubbers for objects conservation applications. The main problem is that silicone rubbers often leave behind liquid and solid residues on objects after they are used. While it may be possible to physically remove the solids, the liquid residues often result in the development of a stain on the surface of the object where the silicone rubber had been applied. The question becomes, what is the chemical make up of these stains and can they be removed using solvents?

Why are we using these silicone polymers in the first place?
• to make casts for recasting
• to allow you to see an image or tool marks inscribed into a object better than you can see them on the object itself (silicone rubbers are homogeneous in color while objects themselves may not be)
• to non-invasively investigate the surface topography of the artifact

The research project entailed selecting eight different silicone rubbers and applying them to a series of different surfaces (plaster discs, limestone, and glass). Following removal of the silicones, attenuated reflectance-fourier transform infrared spectroscopy (ATR-FTIR) was used to determine the chemical make up (O-Si-O and Si-CH3 bonds) and depth of penetration of the liquid residues left behind. Several types of mass spectrometry (evolved gas, pyrolysis gas chromatography [PYGC-MS]) were used to study the eight rubbers and the molecular weights of the materials that are excreted out of the silicone rubbers and left on the different substrates.

RESULTS AND CONCLUSIONS:

* Hexane can be used to remove some of the staining material. I wasn’t sure how this conclusion was drawn? Regardless, it was a better solvent than either methanol (or was it ethanol) for removing some of the residue.

* When residues were observed, the color of residue was related to the color of the mold/silicome material

* Residues are mainly high molecular weight (HMW) components of the silicone rubber and are in their polymeric form – this wasn’t necessarily an expected outcome but it was what was observed

* It wasn’t possible to do a quantitative comparison of the amount of residue left behind between different rubbers

* Slow setting silicone rubber is bad for porous surfaces and residues can penetrate up to 100 microns into the surface (depending on the porosity of the object)

* Given the same rubber, the amount of residue left behind is a function of the material its applied to (intuitive?)

*Siloxane residues are comparable for quick setting rubbers

*Residues maybe reduced, but it is unlikely that they are effectively removed even with non-polar solvents

* There were a couple of others, but future work is to see if barrier coatings (methylcellulose) will help prevent residue deposition.

COMMENTS made following the presentation:

Baltimore museum stopped using silicone rubbers years ago; using silicones on rubbers causes patinas to disappear – patinas were saturated with silicone residues; little bits of set silicone were stuck in interstices of porous surfaces;

• I was surprised – atr is not really ideal for depth of penetration analysis; I also don’t think you can examine an area smaller than 20 um wide; can be hard to measure depths of penetration very accurately)

Any idea how porous the plaster is? Gypsum plaster – can you measure porosity?

Made sure used same batch of plaster throughout the experiments

AIC’s 40th Annual Meeting, The Creation, Implementation, and Safety of Digitally Printed Fabrics in Textile Conservation: Where are We in 2012?, by Miriam Murphy

Author Miriam Murphy, Kress Conservation Fellow, Museum Conservation Institute, and National Museum of African History and Culture, Smithsonian Institution, presented a review of digital printing techniques and their use in textile conservation. This was a great refresher for colleagues who have not kept up with advances over the past decade, including your’s truly.

There are seven steps in producing digitally printed textiles. Step 1 is the digital capture, using scanner or camera. Often this is done by the conservator.

Step 2 is image processing, which is bet left to the printer in order to produce accurate results and avoid hair-tearing-out by the conservator.

Step 3 is color management, for which a color blanket is an essential tool. This is a full printout of colors on the chosen substrate, best compared to the source object in the same lighting as eventual display, ie the gallery or historic house. The small fee for this color blanket is well worth the investment.

Step 4 is the printing process. Although 600-700 dpi is available, 300 is usually plenty good. Printers can print up to 138″ wide and are often constrained only by the size of the image file.

Step 5 is choice of ink. Pigment based inks are the best choice because they require no pretreatment to the substrate and dry with heat. They are susceptible to breakdown in extreme light conditions and with abrasion and much washing. Dark colors can also be hard to achieve and contrast between adjacent dark colors is not always great. Museum conditions usually can accommodate these limitations.

Step 6 is choice of substrate. There are many, many available substrates, but cotton remains the best choice for museum applications. The weave structure of the original does not have to match because the image will provide this detail. Fabrics are available form the printer or from TestFabrics or Jacquard Inkjet Fabric Systems.

Step 7 is pre and post treatment assessment–I confess my notes are sketchy about this step.

If you are interested in speaking with digital print houses, Ms Murphy suggested several including Super Sampler, First2print, LTS Design Service Corp and Digifab, most of which are in NYC, I believe.

The benefits of digitally printed fabrics in museums has been outlined elsewhere, but highlights include quick turnaround, high resolution, and increasingly small dye runs. Why aren’t we all using this technology??!!

AIC’s 40th Annual Meeting, A Successful Treatment Method for Reducing Dye Bleed on a 19th-Century Sampler, by Katherine Sahmel and Laura Mina

Conservation of an 1832 Scottish sampler in the collection of the Philadelphia Museum of Art was begun by Winterthur student Katherine Sahmel while an intern at the PMA and continues with FIT student Laura Mina, the current intern.

This outstanding sampler is part of the Whitman collection and is notable not only for its design but also for its provenience and the existence of photographs of the main building depicted in the embroidery. Prior to acquisition, the sampler was apparently washed causing extensive bleeding of green and red dyes. It has not been exhibited due to this unfortunate condition.

The dyes were analyzed by Ken Sutherland using FTIR, identifying Indigo Carmine as the probable blue component of the fugitive green dye.

Initial tests to reduce the dye bleeding with standard solvents and surfactants were not fruitful so Ms Sahmel applied the modular cleaning system developed by Richard Wolbers. Tests on small samples of threads from the back of the sampler led to the choice of a combined cleaning solution of EDTA (ethylenediaminetetraacetate)1% and TEA (triethylanolamine) .5%.

This system for cleaning requires extended contact with the textile, minimal wetting, and protection of surrounding embroidery threads. Cyclododecane was applied to the front and back adjacent embroidery yarns. A poultice of cleaning solution in methyl cellulose was then prepared and applied to the dye bleed. After treatment the methyl cellulose was removed and flushed with revcerse osmosis water before drying the treated area under suction.

The pros to this treatment was successful removal of dye bleed with minimal effect on adjacent threads. Cons include difficulty in clearing the methyl cellulose poultice and the high ph of the cleaning solution on the wool threads. When Laura Mina took over the project she modified the poultice to use agaros gel, which is easily prepared and removed. The cleaning solution was adjusted to add more TEA.

This research has wise applications in textile conservation, and sampler conservation in ap[rticular. It is non hazardous and requires no fume hood. Stay tuned for an exhibit of the Whitman Samplers coming to the PMA.

AIC’s 40th Annual Meeting, Repair of 20th-Century Leavers Lace, by Annie-Beth Ellington

Lever’s Lace is a type of machine-made lace that provides a similar product to hand-made bobbin lace. Its structure and relatively low-status in museum collections have made it an uncommon target for conservation treatments. The author’s graduate thesis research for her MA at the University of Rhode Island both brings to light this historic textile and provides guidance in how to undertake stabilization of damaged samples.

In 1813 John Lever modified a loom to make Lever’s Lace, and subsequent addition of Jacquard technology in 1849 increased the range of the product. It was imported to the US in 1910 to make mosquito netting and other simple structures, eventually creating the decorative lace familiar to many people. Lever’s lace consists of a ground of twisted warps. Patterns or ornaments outlined by a heaver thread are accomplished with bobbins.

The author experimented with mock-ups of the structure to better understand the challenges of repairs. She then tensioned a piece of damaged lace over a black fabric-covered board. A photocopy of the pattern area was inserted beneath to act as a guide. Using a microscope, she floated 40 denier nylon threads across areas of loss following the pattern. The author quickly found that intervention could cause additional unraveling of damages areas, so she changed to using Jade adhesive on broken thread ends prior to repairs.

Repair of Levers Lace is slow and dyeing nylon thread to match colors would only add to the project time. However with further development this technique will guide future conservators.