44th Annual Meeting & 42nd Annual Conference – Objects Session, May 16, "The Aftermath of Mends: Removing Historic Fabric Tape from Tlingit Basketry" by Caitlin Mahony

The Aftermath of Mends: Removing Historic Fabric Tape from Tlingit Basketry, presented by Caitlin Mahony and Teri Rofkar
The talk began with an introduction from Teri, who reminded us to be thankful to the caretakers of the land in Montreal. She and Caitlin then shared their presentation of a Mellon fellow project at the National Museum of the American Indian on removing a series of historic mends from Tlingit basketry. This project served as an opportunity to “reactivate” the baskets in their collection.
Teri read from a book entitled for Healing Our Spirit, sharing a Tlingit Oratory which advocated us to “apply kindness to open wounds,” an interesting perspective on the state of the baskets prior to conservation.
File_000 (1)
After seeing the image above of one of the first mother baskets, the audience was introduced to the history of Tlingit basketry. The primary material of these baskets is spruce root, some of which is dyed. Originally constructed as functional objects, they were eventually woven for the tourist trade, which helped the community transition from a subsistence to a market economy. When in use, Teri mentioned the baskets could be expected to have approximately a 100 year life span given heavy use.
There are now over 700 Tlingit baskets in the NMAI, many of which suffer from condition concerns. These include rips, tears, losses, and fold lines. Patterns of damage indicated that the dyed spruce root regions may be contributing to weakness. In 2011, the NMAI hosted a Mellon fellow research project that investigated the processing of spruce root at a cellular level. This set the stage for the more recent project which was focused on treatment.
In the first half of the 20th century, a repair campaign on pottery in the NMAI collection was documented. An image shared in the lecture showed a row of gentlemen seated behind a table covered with ceramics. A similar campaign was likely undertaken with the Tlingit baskets, though there is no documentation. Most of the repairs used hide glue or cellulose nitrate impregnated fabric strips that were painted with oil paints. Either the colors were never close matches or they have shifted significantly with time, but the repairs are currently aesthetically incongruous.
Of the 580 baskets investigated, 130 had historic mends. Of these, 24 had major repairs, which was defined as 20+ mends or a mend that obscured a sizable area of the wall or base. Tears were frequently found adjacent to these mends, likely due to the greater strength of the adhesive than the basket. Distortion was also noted, likely due to the effects of the drying of the adhesives. They also caused the removal or redeposition of tannins, dirt, and residue from the baskets, resulting in tide lines.  Given the current condition, many of the baskets could not be exhibited, studied, or handled. Thus, the baskets were ‘inactive’ and no longer serving either their original or adopted functions.
NMAI hosted a three-day conservation workshop in April with representatives from museums with strong Tlingit basket collections. One goal of the workshop was to form an integrated protocol, as well as to study the technology and develop action points to create a path forward.
Since the workshop, NMAI has undertaken extensive documentation, consulted with the Tlingit community to correct and confirm catalog information, identified the wrapped weft material, which had been called false embroidery, and created digital reconstructions. These computer-generated images were created by Laurie Stepp and illustrate how the baskets would have looked when new. They also analyzed the color values, as the tannins are oxidizing and the dye fading.
After processing this information, experimentation was undertaken to develop a treatment approach. The primary goal for the baskets with major repairs involved taking down the fabric mends. Mockups provided by the Getty were used to test various methods. First focusing on the hide glue repairs, Caitlin found that water caused tide lines and blanching when applied with less control. However, when applied in the form of 2% agarose gel, the adhesive was softened and no tide lines formed. This approach was then used in treating the baskets. No barrier layer was necessary and they could work in multiple locations at the same time. They covered the agarose with plastic and gently weighted the gel to reduce evaporation and improve contact. Caitlin found a dwell time of approximately 45 minutes was effective. The fabric tape and residual adhesive could be mechanically removed with wooden skewers in the direction of the stitches; no adverse effects were noted from the treatment.
However, once the fabric was removed, areas of basketry were revealed whih had been protected from light exposure, indicating what the colors may have looked like when the baskets were first collected. This brought up the question of the aesthetic reintegration of the areas of previous repair. Conservators discussed this with curators and considered what the baskets might gain and loose through reintegration. The repairs are part of the baskets’ stories, but they are also visually distracting. This is an ongoing conversation.
Storage was designed for each object, based on individual needs and condition concerns.  NMAI is also exploring how to improve access to this collection. They want to ‘reconnect the disturbed baskets’, and are currently loading tablets with the images and information which can be distributed to schools and used for other programs. An ongoing goal of the project is to continue collaboration between institutions to facilitate knowledge sharing. The NMAI also wants to connect with the contemporary weaving community, which Teri described as fragile, explaining that there were not many weavers 100 years ago and that there are even less now. Contemporary weavers work on commissions – so let’s ask people to weave again!
The talk ended with Teri saying, ‘Gunalcheesh, Ho, Ho. Thank you from the bottom of my heart.’ With this, she extended gratitude to the baskets and the remarkable women who wove them.
After the presentation, two questions were asked:

  1. Q: Did NMAI find any traditional repairs?  A: Yes, which included the weaving of new spruce roots, the combination of parts of baskets, such as the bottom of one with the walls of another, and the repurposing of large baskets to extend their lifetime.
  2. Q: The agarose gel approach worked for the hide glue, what about with the cellulose nitrate mends? A: No, agarose did not work and acetone has negative effects on the baskets. They plan to try saturating the areas with D3/D4 silicone solvents to mask the materials and create a dam, but this is an aspect of future work.

This post was written from my personal notes, which may contain errors or inaccurately represent the author’s original intentions.

44th Annual Meeting, Objects Session, May 17th, “The Use of Gums and Resins in Archaeology and Microchemical Tests for their Identification,” by Christina Bisulca

Christina Bisulca presented a fascinating paper that not only described the source of and uses for pine resins and insect lacs but also detailed various methods of testing for these substances in the lab. The Arizona State Museum is home to a collection of 35,000 objects representing every major cultural group in the southwest from Paleo-Indian to the historic period. As part of a conservation and rehousing project made possible by a Save America’s Treasures grant, conservators hoped to analyze and identify adhesive resins present within the collection.

Map
Map showing regions mentioned in the talk

Certain plants and insects are found only within particular regions of Arizona due to the huge range of elevation and environmental biomes within the state. Since three of the most prolific cultures, the Hohokam, Mogollan, and Ancestral Puebloan occupied very different biomes, it was assumed their use of natural adhesives would vary according to location. Creosote lac
 
 
 
 
The Hohokam, for example used creosote lac, a polyester resin derived from an insect on the creosote bush found in desert lowlands. On the more northerly Colorado Plateau, where the Ancestral Puebloans lived, piñon pine was a plentiful source of diterpenoid resin. In general, Bisulca and her team assumed insect lac was used in the south and pine resin in the north.
Initial analysis was done with Fourier Transform Infrared Spectroscopy (FTIR) but researchers had trouble gathering reference plant material. They also realized these high tech, expensive tests are not readily available to many archaeologists, so they used microchemical tests in addition. Since no reliable microchemical test existed for shellac the team developed one based on the pH dependency of color in anthraquinone dyes, which are extracted from lac insects in Asia. In alkaline conditions the dyes turn from orange to purple. The test worked 80% of the time even in their archaeological collection. Where it did not work the resin had likely been charred or highly heated. The results of the tests challenged their assumptions about pine resin being used primarily by the north. In fact the team found more insect lac in the Ancestral Puebloan collection than pine resin. The lac would only have been available to these regions through trade. The researchers also investigated the use of each material. Bisulca used arrows, common to all three cultures, to highlight the different uses for each adhesive. Insect lac is stronger and less brittle so was used by each culture, regardless of location, for hafting the arrowheads to the shaft.
lac ballPotbiface
Overall, Dr. Bisulca’s talk was extremely informative and used excellent images to portray her ideas. The images she used of the lacs and resins as they are found in nature and on ethnographic objects helped to clarify the differences between the source and use of each. I have to admit I had not considered the significance of these resins in terms of their use in tracing trade routes and cultural practices. I am curious to know what similar substances would have been used by Eastern and Plains area cultures and how well such resins would be preserved in damp archaeological environments. This will certainly change the way I approach native material at my own site.
All images are from a poster on insect lac by Christina Biscula available here.
Information about the authors is available from The Arizona State Museum’s website.

44th Annual Meeting, May 17, Objects, Conservation and investigation of ancient bodies at Abydos– Challenging work in post-revolutionary Egypt. Lucy-Anne Skinner and Mohamed Ahmed Ibrahim.

Lucy-Anne Skinner spoke about the conservation of human remains at the site of Abydos, Egypt. Working for the Institute of Fine Arts, New York University project, Lucy had to engineer some novel solutions when two unusual burials needed to be block lifted. Lucy explained that block lifting an entire burial is not common at Abydos, as most graves are fully excavated in the field. Two graves excavated in the 2012 season in the North Cemetery presented unusually complete assemblages of grave goods,  with one wearing a beaded headdress over well-preserved hair, and these factors prompted the conservators to block lift rather than to try to treat the components in situ.

The team of workmen working with the conservator helped build a wooden frame and slide metal sheets underneath, so that the entire burial could be lifted. Foil was used as a barrier layer, and expandable spray foam was used to lock components into place so that the burial could be transported back to the lab and eventually (in another field season) flipped over to work from the bottom to stabilize the lower portion of the coffin before addressing the human remains and other components.  Lucy showed many details of the extraordinary finds including beautiful hippo ivory clappers. Though this project began in 2012, conservation of the burials was only completed a few days before this talk was presented (really!). Political instability in Egypt and the extraordinary logistical challenges surrounding excavating in a country undergoing political and social upheaval complicated the timeline and created extra challenges for the conservators.
Transporting a block-lifted burial to the depot at Abydos, Egypt (image courtesy Abydos excavations, Institute of Fine Arts, New York University)
Transporting a block-lifted burial to the depot at Abydos, Egypt (image courtesy Abydos excavations, Institute of Fine Arts, New York University)
For me, the big takeaways were that conservation in the field requires a great deal of planning and then a lot of on-the-fly creativity. Many digs lack a field conservator, but clearly the planning and execution of this complicated project really benefited from having Lucy on site over the course of multiple seasons. The project took several years to complete, so communication and planning in the off-season was needed for a successful outcome. Particularly challenging issues of working within Egypt while in the middle of a period of crisis were dealt with admirably by Lucy and her colleagues.

44th Annual AIC meeting, May 17, 2016, “An Unexpected Surface: Research and treatment of a 19th century mounted oyster shell by Froment-Meurice” by Emily Brown

This talk focused on the research and treatment of Froment-Meurice oyster shell artifact made by Emile Froment-Meurice.  The conservation concerns were identification of the corrosion layers and treatment of the metal surfaces.   The artifact was purchased by William Walters in 1878.  It is a composite artifact that depicts two putti discovering a pearl inside of an oyster.  The oyster shell holds a natural pearl in a metal mount.  The mermaid stem and putti are a silver copper alloy, the base is silver with a gold enriched surface and the hinge is a gold alloy.  The oyster shell artifact was damaged and repaired multiple times in the past.  The 1930 photograph from the museum shows the object in one piece.
The main condition issue for this treatment was the heavily tarnished metal surfaces.  The silver and gold elements were nearly black with heavy tarnish overall.  In the 1840s the goldsmiths would often intentionally create a darkened oxidized surface on silver.  In a 2003 French catalogue “Tresors D’Argent” (translated as “Silver Treasures”) two similar shell objects are included, but both have polished and shiny metal elements.  Other artifacts are listed as “oxidized silver and painted sheet metal” objects.  A similar oxidized silver surface can be found on the commemorative shield (c. 1881) by Froment-Meurice in the Art Institute of Chicago labeled as “an elliptical shield of oxidized silver”.
There are a few differences between tarnished silver and oxidized silver.  Tarnished silver is an unintentional patina created by airborne pollutants.  Oxidized silver is an intentional antiqued patination created by chemical compounds.  The small traces of silver chloride found on the surface of the artifacts may be a byproduct of silver chloride that was used to antique the surface of silver objects.  With this in mind, the decision was made to clean the silver, but not remove the black surface.  The gold elements would be cleaned until bright.
The gold and gilt silver components could not be cleaned with abrasion or normal polishing.  Instead an acidified thiourea xantham gum gel was used to clean the surface.  The gel as applied with a cotton pad and rinsed with water.  The dwell time was kept to a quick 5 – 10 seconds.  The process was repeated as needed.  For the metal clasp, mylar was placed between the metal and the shell to protect the surface of the shell.  The gel was applied with a brush and then rinsed with the use of chem-wipes and a bristle brush.  The gel cleaning produced a bright and shiny surface.  The process had excellent control and a quick removal of the material was possible.  The putto were adhered into place, but the shell was left partially unassembled for transportation.  A complex and well-designed storage and shipment box was created for the artifact.  This storage box was featured in the STASH flash III on May 14th and will be published on the AIC STASH website.

44th Annual AIC meeting, May 17, 2016, "When in Rome, do as the Romans do? The Conservation of an Italian Marble and Micromosaic Tabletop” by Elizabeth La Duc

Elizabeth La Duc gave an engrossing talk in the Objects Specialty session on the conservation treatment of a 19th century Pietre Dure and micromosaic tabletop belonging to the Josiah Quincy house of Historic New England. The stone tabletop, positioned on top of a painting and gilded wooden base, had and been conserved in the past.  Her treatment was readdressing this past treatment and returning it to exhibit-able condition.
Pietre Dure translates into English as “hard stone”.  The Pietre Dure portions consist of decorative stones set into the carved channels within the black marble base and adhered with a rosin and beeswax.  The micromosaic areas are images made up from tiny tesserae called smalti.  The smalti are cut to shape and inserted into an adhesive of linseed oil, lime and marble dust.  The top surface was polished to a flat surface and the gaps between the tesserae were filled with tinted beeswax.  This beeswax can be seen under ultraviolet light, but it has often been lost through over cleaning and use.
The table top was in poor condition.  The four sections were poorly adhered and slightly misaligned.  A large crack in the stone tabletop ran across the middle of the tabletop and transected both the Pietre Dure and the micromosaic elements of the table.  Two stone inlays were missing and there were losses in the micromosaic along the central break.
The conservation treatment started with a surface cleaning of calcium saturated water with the pH raised to 8.5 with ammonia and added drops of Triton.  Acetone was wicked into the old joins to dissolve the older restoration adhesive.  B72 and microballons were used to glue the pieces back together.
For the conservation of the Pietre Dure portions two options were considered.  In Florence, the missing elements would have been replaced with new cut stone.  The Pietre Dure objects are decorative and require a high level of finish.  Another Italian treatment option is to cast crushed stone and resin to recreate the missing inlays.  This second approach was chosen and the new Pietre Dure elements were created with tinted epoxy bulked with fumed silica cast into silicone rubber molds.  In some areas it was necessary to back of the Pietre Dure areas of loss with a layer of Japanese tissue coated with B72.  The epoxy elements were then cast directly into the loss.  Gamblin conservation colors were used to finish off the top of these fills and a layer of Acrysol WS24 was brushed on top to give a polished shine.
The micromosaic repairs were based on similar micromosaic designs.  Since the micromosaics were mass produced with only a small range of designs, similar images could be used as guidelines for decorative elements on the fills.  The areas of loss in the micromosaics were backed with acid free matt board topped with a layer of modostuc.  Gamblin conservation colors were used to inpaint the surface in two steps.  The first step painted the background colors and the second step painted the individual small tesserae.
This was an elegant and well executed treatment with results that were aesthetically pleasing and reversible.  Under close examination, the areas of filled loss are distinguishable from the original material.  This was a great talk and I hope to get a chance to work on micromosaics someday!

44th Annual Meeting – Objects-Wooden Artifacts Session, Monday 16 May 2016, "The study of boxwood prayer beads and miniature altars from the Thomson Collection at the Art Gallery of Ontario and the Metropolitan Museum of Art” presented by Lisa Ellis

Lisa Ellis, Conservator of Sculpture and Decorative Arts at the Art Gallery of Ontario (AGO), presented collaborative work on the study of boxwood prayer beads and miniature altars from the early 16th century (c. 1500-1530). The beads and altars are very small, complex, and intricately carved artifacts whose construction has not been well characterized. Teams at the AGO and the Metropolitan Museum of Art (MMA) are exploring the carving techniques and joinery strategies using careful examination, micro-computed tomography (µCT scanning), and physical deconstruction of select artifacts to better understand how the pieces were created.
Because of their depth and small size, traditional photography has been inadequate to capture the various layers in focus within one image, making distance sharing and comparative work impossible. In order to better share between institutions and scholars, the AGO set out to photodocument these artifacts with high resolution images that are in focus throughout the depth of the artifact. In order to do this, they are taking a series of photos at various focal depths, then stacking the images to maintain sharpness. The image quality is profoundly improved from the old hazy images that made it impossible to understand the detail.

 Workshop of Adam Dirksz, Prayer bead, AGOID.29365. Detail showing “The Coronation of the Virgin.” The Thomson Collection of European Art © Art Gallery of Ontario.

Prayer bead, AGOID.29365. Detail showing “The Coronation of the Virgin.” The Thomson Collection of European Art © Art Gallery of Ontario.

 
Through preliminary x-radiography, they found that the artifacts can be grouped in to two broad classes: artifacts created in simple relief and artifacts created with a complex design. The complex artifacts were then µCT scanned, revealing the multiple elements joined together. Using medical imaging software, they were able to better understand the parts and see that the beads were created in layers. With the software, the various layers could be virtually deconstructed so that each layer could be examined and stacked, as if each piece were separate. At the MMA, Pete Dandridge, Conservator and Administrator, was able to disassemble a bead to physically see the pieces, which further helped to interpret the µCT data and reinforced the understanding of the layers. Since not all artifacts can be taken apart, the µCT scans provided to be invaluable in examining the construction and documenting the process. One example showed a bead attached to a rosary that had multiple roundels set into the main structure. The roundels could be virtually removed with the µCT scans and software, revealing a numbering system beneath.
Workshop of Adam Dirksz, Prayer bead, AGOID.29365. Micro CT scan revealing use of pegs in depiction of “The Coronation of the Virgin.” The Thomson Collection of European Art © Art Gallery of Ontario. Scans courtesy of Sustainable Archaeology at Western University.
Prayer bead, AGOID.29365. Micro CT scan revealing use of pegs in depiction of “The Coronation of the Virgin.” The Thomson Collection of European Art © Art Gallery of Ontario. Scans courtesy of Sustainable Archaeology at Western University.

 

 
In addition to examining the construction, they also looked at the limited polychromy present on some beads. Although most pieces were unpainted, a few pieces had painted details in blue, black, or red. These elements, along with adhesives and coatings, are being analyzed at the MMA and the Canadian Conservation Institute (CCI) with a suite of techniques.
These artifacts and findings about them will be presented in an exhibition, Small Wonders: Gothic Boxwood Miniatures, opening in Toronto on Nov. 5, 2016. The exhibition will feature over 60 boxwood carvings from institutions and private collections across Europe and North America. Following its debut at the AGO, the exhibition will open at the The Cloisters at The Metropolitan Museum of Art on Feb. 21, 2017, before travelling to the Rijksmuseum on June 15, 2017. For more details about the exhibition and related programming visit www.ago.net and follow #miniAGO on twitter and instagram.
For images and further details on the work being carried out at the AGO, visit this link at the CODART eZine: http://ezine.codart.nl/17/issue/45/artikel/investigating-miniature-boxwood-carving-at-the-art-gallery-of-ontario-in-toronto/?id=119#!/page/1
Investigation on these materials have been on-going. For some background on earlier work that started this process, visit this link on the AGO website: http://www.ago.net/idea-lab
Other collaborators not mentioned above include: Alexandra Suda (AGO), Andrew Nelson (Sustainable Archaeology, Western University), Barbara Drake Boehm (MMA – Cloisters), Elizabeth Moffatt (CCI – retired), Jennifer Poulin (CCI)

44th Annual Meeting, May 16, Research and Technical Studies, Visible-Induced Luminescence Imaging: Past, Current and Future Applications in Conservation Research, Dawn Kriss and Anna Serotta

I was excited to see the most recent update on VIL imaging as it is an accessible imaging technique that can be used to localize pigments with specific characteristics. It is useful for anyone interested in painted surfaces, and can be used in conjunction with other multispectral imaging, or as a standalone technique.
The basic idea is that you need a light source to produce visible light, a camera with its infrared filter removed, and a bandpass filter to limit the type of light that gets to the camera sensor, along with some standards to help process the images. The pigment particles on the object are excited in the visible range, and emit infrared radiation which is detected by the modified camera. This technique can be used to detect trace remains of pigments that are all but undetectable to the naked eye. The technique was developed by scientists from the British Museum and the Courtauld Institute (see Verri et al., 2009) [1].
In the case studies shown in Dawn and Anna’s presentation the focus was on Egyptian blue, which produces luminescence in the infrared (~910nm) when exposed to visible light. Optimizing the capture and processing protocols will mean better results and hopefully, a means of standardizing and sharing information between conservators working in different labs.  While VIL is gaining popularity as more museums add it to their workflow (for example. as part of the APPEAR project spearheaded by the Getty), the technique is still being developed, with much more progress on the horizon. Dawn and Anna reported on results of a survey of VIL users to show where progress has been made and where we can still expect some improvements in the technique.

gif showing VIL and normal illumination images of Brooklyn Museum's portrait, Noblewoman, ca. 150 C.E. Encaustic on wood. Brooklyn Museum, Gift of the Ernest Erickson Foundation, Inc., 86.226.1, image courtesy Brooklyn Museum
Click for larger image and to view transition! A gif showing VIL and normal illumination images of Brooklyn Museum’s portrait, Noblewoman, ca. 150 C.E. Encaustic on wood. Brooklyn Museum, Gift of the Ernest Erickson Foundation, Inc., 86.226.1, image courtesy Brooklyn Museum
Capture: varying light sources
There are many options for lights used for excitation, so choosing a light source that is targeted to your research question is critical. As an example, the authors described work by my classmate Brian Castriota showing that red LEDs with an output centered at 630 nm caused greater luminescence of Egyptian blue compared to white LEDs. More research on the luminescence characteristics of other pigments will help users optimize their light sources to target specific pigments.
Processing: calibration, standards, and protocols 
While many conservators using VIL use the CHARISMA protocols (developed by the British Museum), others are using Photoshop to process the images. Egyptian blue VIL images are usually shown in monochrome, but as the technique is expanded different overlays or crossfades will help communicate the results by registering the images with other photographs, as Dawn and Anna did for the images shown in their presentation. This is one of the greatest advantages of VIL: it’s very easy to understand the images that are generated and easy to communicate the results to the public. However, capturing good metadata and using appropriate standards are critical for the intercomparability of these data in the future. It will be crucial to develop a luminescence scale or target in order to compare images from institutions who may not be using the exact same capture or processing parameters.
What do we have to look forward to? 
While its initial development as a tool for identifying Egyptian blue has led to its popularity among archaeological conservators, it seems like the technique is ripe for more widespread adoption for research into modern pigments, some of which also have unique luminescence properties.
Conservators can use a variety of wavelengths using targeted or tunable light sources (e.g. the CrimeScope, adapted from the forensics field) to survey visible-induced luminescent pigments (other examples of which include dragon’s blood, Indian yellow, Han blue, cadmium red and yellow). Dawn and Anna showed an example of imaging surveying cadmium pigments used in Stuart Davis’s Mellow Pad carried out by their Brooklyn colleague Jessica Ford. For more on the work from the team at the Brooklyn Museum, see their recent blog post here.
References.
[1] Verri, Giovanni, et al. “Assyrian Colours: Pigments on a Neo-Assyrian Relief of a Parade Horse.” The British Museum Technical Research Bulletin 3 (2009): 57–62.

New JAIC issue online now

JAIC coverThe latest issue of JAIC (Journal of the American Institute for Conservation) is now online, and print copies are mailing shortly. This issue, Vol. 53, No. 2, features the following articles:

  • EDITORIAL, by Julio M. Del Hoyo-Meléndez, Editor-In-Chief
  • SHORT COMMUNICATION: GOBERGE, SHIMBARI, GO-BARS: THE USE OF FLEXIBLE STICKS FOR CLAMPING, by Tristram Bainbridge, Shayne Rivers, Yoshihiko Yamashita, Andrew Thackray, Nicola Newman
  • CHOOSING AN ADHESIVE FOR EXTERIOR WOODWORK THROUGH MECHANICAL TESTING, by Rian M. H. Deurenberg-Wilkinson
  • SOURCE CODE ANALYSIS AS TECHNICAL ART HISTORY, by Deena Engel and Glenn Wharton
  • RAISING MERET-IT-ES: EXAMINING AND CONSERVING AN EGYPTIAN ANTHROPOID COFFIN FROM 380–250 BCE, by Kathleen M. Garland, Johanna Bernstein, Joe Rogers
  • BOOK REVIEWS, by Vanessa Muros and Cybele Tom

AIC members and journal subscribers have online access to these articles now, before the print issue arrives. We hope you enjoy these articles, which bring some very interesting techniques and research to light.

Read more about the journal at http://www.maneyonline.com/loi/jac, or review the submission guidelines and JAIC style guide at http://www.conservation-us.org/jaic.

Survey on methods for cleaning and protecting historical lead

A research team from the National Center for Metallurgical Research (CENIM-CSIC) is carrying out a study about the methods of cleaning and protection of historical lead. As part of this study, the investigators hope to learn about the methods applied by professionals and their personal experience with them. The survey should take 10-15 minutes and it is available until July 15th at: http://goo.gl/forms/80sJsl3Nx9  Please feel free to forward the link to interested colleagues.
The results will be published afterwards, and will be sent to interested participants. To receive results, please leave your email in the contact details section of the survey. For more information about this study, please contact t.palomar@csic.es. Thank you in advance for your collaboration.
Dr. Teresa Palomar Sanz
Centro Nacional de Investigaciones Metalurgicas (CENIM) Consejo Superior de Investigaciones Cientificas (CSIC) Avenida Gregorio del Amo, 8.
28040 Madrid
Spain

43rd Annual Meeting – Objects Specialty Group Session, May 16, 2015, "Silver or gold? Surprising Challenges in Cleaning a 19th-Century Persian Water Pipe" by Ariel O'Connor, with Julie Lauffenburger, Meg Craft, and Glenn Gates

In keeping with the conference theme of Practical Philosophy, or Making Conservation Work, Ariel O’Connor, currently at the National Air and Space Museum and formerly at the Walters Art Museum in Baltimore, presented a talk where an imperfect treatment method proved to be the best option.  A nineteenth century Persian water pipe, or nargile, made of gilded silver and elaborately decorated with gemstones, was heavily tarnished and needed to be cleaned in preparation for an upcoming exhibit.  The water pipe was first analyzed with XRF to determine the treatment; XRF indicated silver with copper, gold, and lead, but no mercury, suggesting the object was gilded with some process other than mercury gilding.

Persian Water Piper, after treatment.  Source: www.thewalters.org
Persian Water Pipe, after treatment. Source: www.thewalters.org

Test cleanings were done with several standard methods for reducing tarnish mechanically: cosmetic sponges, Duraglit polish, precipitated calcium carbonate, Long Shine silver polishing cloth, and Mars Erasers.  Acidified thiourea, a chemical method of reducing tarnish, was not initially considered because of research showing the problems of thiourea – leaching of copper, microetching, and long-term detrimental effect of thiourea residues.  (See for example, a recent article by Contreras-Vargas et al, “Effects of the cleaning of silver with acified thiourea solutions” in Conference Proceedings of Metal 2013.)  While the mechanical methods, especially the erasers and sponges, were easy to use, the final appearance of the polished surface in the test cleaning areas was not as golden as expected.
Analysis with XRF led to a frightening conclusion: even the gentlest mechanical methods, such as a cosmetic sponge, removed gold from the surface.  And as the object was gilded with a method other than mercury gilding, the gold layer was already very thing.  Analysis after a test cleaning with thiourea, however, did not show the same loss of gold.  The decision to clean the object with thiourea was reluctantly made.  Steps were taken to use thiourea as safely as possible: dwell time was minimized, the surface was immediately rinsed with deionized water, and the work was performed in the fume hood because of the generation of poisonous gases.  O’Connor introduced a novel technique for applying and rinsing the thiourea.   Strips of non-woven cotton Webril Handi-pads were placed on the object then wetted with thiourea applied by dropper; rinsing was also performed with the handi-pads.  Cotton swabs were used as little as possible because of the possibility of abrasion of the surface.
The treatment raised the important question of when is it acceptable to use a method that has been shown to be damaging.  O’Connor articulated why, on this occasion, chemical cleaning with thiourea was the lesser of two evils.  I look forward to seeing more research on the topic of cleaning gilded silver as well as discussion of the ethics involved in this treatment.